THE ASTRONOMICAL JOURNAL VOLUME 112, NUMBER 2, PAGE 491 AUGUST 1996 LATE-TYPE STARS IN M31. II. C-, S-, AND M-STAR SPECTRA JAMES P. BREWER European Southern Observatory, Casilla 19001, Santiago 19, Chile Electronic mail: jbrewer@eso.org HARVEY B. RICHER Department of Geophysics and Astronomy, University of British Columbia, 129-2219 Main Mall, Vancouver, B.C., V6T 1Z4, Canada Electronic mail: richer@astro.ubc.ca DENNIS R. CRABTREE Dominion Astrophysical Observatory, Herzberg Institute of Astrophysics, National Research Council, 5071 W. Saanich Road, Victoria, B.C. V8X 4M6, Canada Electronic mail: crabtree@dao.nrc.ca ABSTRACT We present spectra of AGB stars in M31 for which observations had been previously secured using a four-band photometric system (FBPS). The FBPS had been used to identify M-, S-, and carbon-star (C-star) candidates, and we use the spectra to show that the FBPS did an excellent job at identifying C- and M-stars. Of the 48 C-stars for which spectra were obtained, 7 have strongly enhanced 13C bands (J-stars), 2 have strong Halpha emission, while 3 are found to exhibit enhanced Li absorption (Li-stars). Both the J- and Li-stars are fainter than predicted by current theoretical models, while the colors of the Halpha stars suggest they may be in the terminal phases of their evolution. The C2 and CN bandstrengths of the C-stars are measured, and no correlation between these bandstrengths and either Mbol or (V-I) is found. It is suggested that this lack of correlation is due to an age spread. The spectra of the first confirmed S-star in M31 is presented, and two evolutionary pathways are suggested to account for this star's high luminosity.